The interest towards bifacial PV technology has increased over the last years, due to its potential capability of obtaining higher efficiencies with respect to traditional monofacial cells. Thus, the aim of this work is to present an experimental investigation on an innovative photovoltaic technology, such as the bifacial solar cells based on monocrystalline substrate. This analysis is mainly based on the determination of the current density/voltage, power density/voltage, External Quantum Efficiency (EQE) and Laser Beam Induced Current (LBIC) characterization. Interesting results are presented and discussed, demonstrating that the bifacial silicon solar cells can be a very promising technology with high electrical performances and efficiency.