Noble-metal clusters dispersed in glass matrix are of great interest for their technological applications such as heterogeneous catalysis, in the realization of non-linear optical devices, in sensor technology, for absorption control in solar reflecting glasses ( coatings) etc. The physical properties of these materials strongly depend on cluster concentration, size distribution and on their structural and chemical nature. High spatial resolution structural and analytical characterization techniques are needed to understand the cluster formation mechanism and the physical properties of these materials. In this work, palladium clusters dispersed in ORMOCER matrix via a modified sol-gel process are structurally and chemically characterized by conventional transmission electron microscopy, high-resolution electron microscopy, electron nanodiffraction and X-ray diffractometry, in order to obtain information on the clusters shape …