Modification of the van der Waals interaction at the Bi2Te3 and Ge(111) interface

Data di pubblicazione: 12 Feb 2021

RivistaFonte dati: OPENALEXTipo OpenAlex: articleOpen Access
Autori: Kenji Nawa, Demie M. Kepaptsoglou, Arsham Ghasemi, Philip J. Hasnip, Guillermo Bárcena‐González, Giuseppe Nicotra, Pedro L. Galindo, Quentin Mathieu Ramasse, Kohji Nakamura, Susannah C. Speller, Barat Achinuq, T. Hesjedal, Vlado K. Lazarov

We present a structural and density-functional theory study of the interface of the quasi-twin-free grown three-dimensional topological insulator ${\mathrm{Bi}}_{2}{\mathrm{Te}}_{3}$ on Ge(111). Aberration-corrected scanning transmission electron microscopy and electron energy-loss spectroscopy in combination with first-principles calculations show that the weak van der Waals adhesion between the ${\mathrm{Bi}}_{2}{\mathrm{Te}}_{3}$ quintuple layer and Ge can be overcome by forming an additional Te layer at their interface. The first-principles calculations of the formation energy of the additional Te layer show it to be energetically favorable as a result of the strong hybridization between the Te and Ge.

Fonte
Physical Review Materials
Volume
5
Fascicolo
2
Citazioni
4
ID archivio
503e855586c086d644c09a7e40e7d9d5