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Type: 
Journal
Description: 
The changes induced in the amorphous regions of poly(ethylene terephthalate) as a consequence of recrystallization processes, taking place after cold-crystallization at Tc = 100 °C, are analyzed by means of isothermal dynamical mechanical spectroscopy and microindentation hardness. Overall, a recrystallization process at either 115 or 125 °C causes an increase of the rigidity within the amorphous domains confined by the crystals. Microhardness measurements carried out at room temperature reveal that recrystallization leads to an enhanced mechanical performance of the amorphous regions. The analysis of isothermal segmental relaxation patterns recorded in a frequency interval of 10−3–60 Hz indicates the appearance of two distinct contributions, which find correspondence with observations by broad band dielectric spectroscopy on the same systems. The faster one is ascribed to segmental relaxation …
Publisher: 
Elsevier
Publication date: 
22 Jun 2011
Authors: 

Araceli Flores, Francisco José Baltá-Calleja, G Di Marco, S Sturniolo, M Pieruccini

Biblio References: 
Volume: 52 Issue: 14 Pages: 3155-3162
Origin: 
Polymer