Lithium fluoride is an insulating material with outstanding optical properties, among them wide optical transparency. Its ionizing radiation sensitivity allows the formation of primary and aggregate point defects, known as color centers, some of which are laser active in the visible and near-infrared even at room temperature. Among their peculiarities, the simultaneous light emission in the green-red wavelength interval under optical excitation in the blue spectral range is suitable for the realization of solid-state photonic light sources, miniaturized optical amplifiers and lasers compatible with integrated optical circuits. Despite the material’s low refractive index, broad-band light-emitting color-center active waveguides were realized at the surface of lithium fluoride crystals and thin films by direct writing with low-energy electron beams and light ions. Due to the complex behavior of radiation-induced defects at high …