Type:
Journal
Description:
The potential of resonant inelastic soft x-ray scattering to measure 4 f crystal electric-field excitation spectra in Ce Kondo lattices has been examined. Spectra have been obtained for several Ce systems and show a well-defined structure determined by crystal-field, spin-orbit, and charge-transfer excitations only. The spectral shapes of the excitation spectra can be well understood in the framework of atomic multiplet calculations. For CeCu 2 Si 2 we found notable disagreement between the inelastic x-ray-scattering spectra and theoretical calculations when using the crystal-field scheme proposed from inelastic neutron scattering. Modified sets of crystal-field parameters yield better agreement. Our results also show that, with the very recent improvements of soft x-ray spectrometers in resolution to below 30 meV at the Ce M 4, 5 edges, resonant inelastic x-ray scattering could be an ideal tool to determine the crystal …
Publisher:
American Physical Society
Publication date:
25 Apr 2016
Biblio References:
Volume: 93 Issue: 16 Pages: 165134
Origin:
Physical Review B