-A A +A
We have elucidated the mechanism for B migration in the amorphous (a-) Si network. B diffusivity in a-Si is much higher than in crystalline Si; it is transient and increases with B concentration up to 2× 10 20 B/cm 3. At higher density, B atoms in a-Si quickly precipitate. B diffusion is indirect, mediated by dangling bonds (DB) present in a-Si. The density of DB is enhanced by B accommodation in the a-Si network and decreases because of a-Si relaxation. Accurate data simulations allow one to extract the DB diffusivity, whose activation energy is 2.6 eV. Implications of these results are discussed.
American Physical Society
Publication date: 
15 Apr 2008

Salvatore Mirabella, Davide De Salvador, Elena Bruno, Enrico Napolitani, Emanuele F Pecora, Simona Boninelli, Francesco Priolo

Biblio References: 
Volume: 100 Issue: 15 Pages: 155901
Physical review letters