-A A +A
We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies.
American Chemical Society
Publication date: 
27 Apr 2010

Erik Schwartz, Eunhee Lim, Chandrakala M Gowda, Andrea Liscio, Oliver Fenwick, Guoli Tu, Vincenzo Palermo, Rene de Gelder, Jeroen JLM Cornelissen, Ernst RH Van Eck, Arno PM Kentgens, Franco Cacialli, Roeland JM Nolte, Paolo Samori, Wilhelm TS Huck, Alan E Rowan

Biblio References: 
Volume: 22 Issue: 8 Pages: 2597-2607
Chemistry of materials